Syntactic constraints. Python is a syntactically simple language with fairly strong constraints on what can and can't be done without "messing things up" (both visually and with regards to the language parser). There's no obvious way to structure this information so that people new to the concept will think, "Oh yeah, I know what you're doing." The best that seems possible is to keep new users from creating a wildly incorrect mental model of what the syntax means.
There have been a number of objections raised to this location -- the primary one is that it's the first real Python case where a line of code has an effect on a following line. The syntax available in 2.4a3 requires one decorator per line (in a2, multiple decorators could be specified on the same line), and the final decision for 2.4 final stayed one decorator per line.
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Did you get it? We just applied the previously learned principles. This is exactly what the decorators do in Python! They wrap a function and modify its behaviour in one way or the another. Now you might be wondering that we did not use the @ anywhere in our code? That is just a short way of making up a decorated function. Here is how we could have run the previous code sample using @.